Abstract
The geochemical alterations occurring in the pedosphere due to industrial activities represent a central problem in modern ecology. This study comparatively assesses specific shifts in the ecological, chemical, and biological parameters of soils within the impact zones of three industrial sectors: a metallurgical combine, a chemical plant, and a thermal power plant. Analyzing 120 soil samples collected from a depth of 0-40 cm, parameters including heavy metals (Pb, Cd, Zn, Cu), pH, soil organic carbon (TOC), and microbial biomass carbon (MBC) were measured. Results indicated that in the metallurgical zone, lead and cadmium exceeded permissible limits by 6.2 and 4.8 times, respectively, forming an acute toxic anomaly. The chemical industry zone exhibited severe soil acidification (pH 4.8) and a 34% degradation of organic carbon. Meanwhile, thermal power plant emissions disrupted soil porosity via ash deposition. These findings provide a fundamental basis for optimizing regional environmental monitoring systems.
References
1. Li X, Zhang M, Liu J, Wang Y. Heavy metal pollution and ecological risk assessment of soils around a typical metallurgical industry complex in arid regions. J Hazard Mater. 2021;412:125203.
2. Schmidt R, Muller K, Hoffmann H. Cadmium and lead accumulation in agricultural soils adjacent to legacy smelting operations: A decadal perspective. Sci Total Environ. 2022;834:155342.
3. Zhao Q, Chen Y, Sun L, Wang X. Soil acidification and carbon depletion in chemical industrial zones: Mechanisms and microbial responses. Soil Biol Biochem. 2023;178:108924.
4. Kumar V, Sharma A, Pandita S. Fly ash deposition and its implications on soil physical properties and enzymatic activity near thermal power plants. Environ Pollut. 2020;266:115243.
5. Petrov IN, Sokolov AA. Geochemical barriers and heavy metal migration in technogenic soils. Eurasian J Soil Sci. 2019;8(2):145-156.
6. Wang F, Liu S, Peng X. Interactive effects of soil pH and heavy metals on soil microbial biomass and basal respiration. Ecotoxicol Environ Saf. 2021;220:112354.
7. O'Connor D, Hou D, Ok YS. Phytoremediation of heavy metal contaminated soils: Progress and bottlenecks. Crit Rev Environ Sci Technol. 2020;50(12):1230-1265.
8. Garcia-Sanchez M, Fernandez E. Soil organic carbon dynamics under chronic industrial aerosol exposure. Agric Ecosyst Environ. 2022;325:107758.
9. Karimov A, Toshpolatov B. Ecotoxicological assessment of industrial soils using bio-indicators in arid climates. Environ Monit Assess. 2023;195(4):421.
10. Williams P, Davies R. Standardized protocols for environmental sampling in technogenically modified regions. J Environ Qual. 2021;50(3):589-601.
11. Chen H, Zheng C. Synergistic toxicity of polymetallic industrial pollutants on soil urease and catalase activities. Chemosphere. 2022;288:132514.
12. Novikov A, Smirnova E. Chemical buffering capacity of soils under the influence of nitrogenous emissions. Pedosphere. 2020;30(1):89-98.
13. Thompson J, Wright M. Soil porosity degradation due to particulate matter deposition from coal combustion. Geoderma. 2019;345:56-64.
14. Lee S, Park J, Kim H. Spatial distribution and source apportionment of heavy metals in peri-urban agricultural soils. Sci Total Environ. 2024;908:168214.
15. Ali H, Khan E. Biomonitoring of industrial pollution: The role of soil microbial carbon as an early warning indicator. Ecol Indic. 2023;148:110056.